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Ecological impact of arsenic, chromium and lead from application of recovered screened material on Florida soils
Title
Ecological impact of arsenic, chromium and lead from application of recovered screened material on Florida soils.
Creator
Scarlatos, Dimitrios., Florida Atlantic University, Scarlatos, Panagiotis (Pete) D., College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description
Disposal of construction and demolition (C&D) debris is a major problem. During recycling operations, the debris is passed over screens, generating what is called Recovered Screened Material (RSM). Previous analyses of RSM indicated high arsenic (As) levels. Thus, RSM is disposed in landfills in spite of the fact that natural soils may contain As levels higher than the proposed concentrations for soil clean-up goals. RSM samples were collected and analyzed from seven C&D debris recycling...
Show moreDisposal of construction and demolition (C&D) debris is a major problem. During recycling operations, the debris is passed over screens, generating what is called Recovered Screened Material (RSM). Previous analyses of RSM indicated high arsenic (As) levels. Thus, RSM is disposed in landfills in spite of the fact that natural soils may contain As levels higher than the proposed concentrations for soil clean-up goals. RSM samples were collected and analyzed from seven C&D debris recycling facilities and from other sites. The average arsenic content found in RSM ranged between residential and industrial clean-up goals. Chromium and lead levels in RSM were very low. The RSM quality depends mainly on the waste stream. Recycling procedures do not have any major effect on the RSM. Arsenic levels in natural soils showed a wide variability. Almost half of the soil samples had an arsenic level comparable to that found in RSM.
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Date Issued
1998
PURL
http://purl.flvc.org/fcla/dt/15532
Subject Headings
Soil pollution--Florida, Soils--Florida--Environmental aspects
Format
Document (PDF)
The fate of copper in flooded south Florida agricultural soils and its toxicological effects on the Florida apple snail, Pomacea paludosa
Title
The fate of copper in flooded south Florida agricultural soils and its toxicological effects on the Florida apple snail, Pomacea paludosa.
Creator
Rogevich, Emily Catherine, Florida Atlantic University, Brooks, W. Randy, Charles E. Schmidt College of Science, Department of Biological Sciences
Abstract/Description
Agricultural sites have been acquired under the Comprehensive Everglades Restoration Plan (CERP) for the creation of water storage areas. Copper desorption and toxicity to the Florida apple snail (Pomacea paludosa) were investigated using soils from these sites. Copper concentrations in II soils ranged from 5 to 234 mg/kg Cu dw, and when flooded, resulted in overlying water Cu concentrations from 9 to 308 11g/L Cu. Juvenile apple snails exposed to three flooded soils had high mortality and...
Show moreAgricultural sites have been acquired under the Comprehensive Everglades Restoration Plan (CERP) for the creation of water storage areas. Copper desorption and toxicity to the Florida apple snail (Pomacea paludosa) were investigated using soils from these sites. Copper concentrations in II soils ranged from 5 to 234 mg/kg Cu dw, and when flooded, resulted in overlying water Cu concentrations from 9 to 308 11g/L Cu. Juvenile apple snails exposed to three flooded soils had high mortality and decreased growth within 9 to 16 days in two ofthe three soils examined. To assess Cu toxicity to the apple snail at various life stages and water quality parameters, 96 hour acute toxicity studies were conducted. Copper was more toxic to juvenile than adult apple snails. Copper toxicity increased as pH decreased and decreased as DOC increased. Hardness had no effect on Cu toxicity to the apple snail. Copper toxicity was a function of organism age, DOC and pH. Copper accumulation by juvenile and adult apple snails was determined for multiple exposure pathways. For 28 days, juvenile snails were exposed to aqueous Cu and adult snails were exposed to Cu contaminated soil, water and food. Whole body Cu in juvenile snails increased with time. The mean Cu bioconcentration factor (BCF) for juvenile snails was 1493. For adult snails, the dietary exposure pathway resulted in the highest bioaccumulation factor (BAF). Most Cu accumulated in soft tissue. During a chronic aqueous exposure, apple snails exposed to 8-16 flg /L Cu for 9 months had high Cu accumulation and significantly reduced clutch production (8-16 flg /L) and egg hatching (16 flg/L ). Chronic Cu exposure initially decreased growth in juvenile snails, but growth rebounded by adulthood and snails appeared to acclimate to chronic Cu exposure. When apple snails with high tissue Cu were fed to redear sunfish (Lepomis microlophus) Cu transfer was minimal, suggesting that the risk of trophic transfer (bioaccumulation) of Cu from the snail to redear sunfish is low and that biomagnification is unlikely. It is uncertain if other apple snail predators would be at risk for dietary Cu transfer.
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Date Issued
2008
PURL
http://purl.flvc.org/fau/fd/FA00000875
Subject Headings
Soil pollution--Florida, Florida applesnail--Habitat, Florida applesnail--Effect of heavy metals on, Copper--Toxicology, Ecosystem management--Florida
Format
Document (PDF)