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Microbial Induced Degradation in Synthetic Fiber Reinforced Concrete Samples in South Florida
Title
Microbial Induced Degradation in Synthetic Fiber Reinforced Concrete Samples in South Florida.
Creator
Parkinson, Jacqueline Cecile, Presuel-Moreno, Francisco, Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description
Synthetic fiber reinforced concrete sample sets were exposed to two different environments. One set, of six samples, was exposed to filtered seawater in the lab with wet and dry cycles, while the other set of samples was exposed, on a barge, to the marine environment, in the intracoastal waterways, at SeaTech. The samples were exposed for 8 months, and then removed for experimental and mechanical testing. Upon removal, the barge samples were photographed to observe surface organisms that were...
Show moreSynthetic fiber reinforced concrete sample sets were exposed to two different environments. One set, of six samples, was exposed to filtered seawater in the lab with wet and dry cycles, while the other set of samples was exposed, on a barge, to the marine environment, in the intracoastal waterways, at SeaTech. The samples were exposed for 8 months, and then removed for experimental and mechanical testing. Upon removal, the barge samples were photographed to observe surface organisms that were attached to each sample. The barge samples, after cleaning, were then exposed to UV light to observe surface bacteria. The barge samples were also taken to Harbor Branch facility for DNA testing, and then sent in for sequencing. This sequencing was used to identify the organisms that were present inside the concrete samples. An Indirect Tensile Strength Test, IDT, was performed on both sets of samples to observe the first crack, max load, and fracture toughness of each sample. The Barge samples had a lower first crack, max load, and fracture toughness, which means that it took less force to break these samples, than the Seawater samples. As the fiber content increased, the Seawater samples grew stronger, while the Barge samples grew weaker. Also, as the fiber content increased, the biodiversity found on the surface of the Barge samples increased as well.
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Date Issued
2019
PURL
http://purl.flvc.org/fau/fd/FA00013251
Subject Headings
Fiber-reinforced concrete, Florida, Concrete--Deterioration, Microbes
Format
Document (PDF)
THE IMPACT CORROSION HAS ON THE DEGRADATION OF MECHANICAL PROPERTIES OF CARBON STEEL REBARS IN HIGH PERFORMANCE CONCRETE
Title
THE IMPACT CORROSION HAS ON THE DEGRADATION OF MECHANICAL PROPERTIES OF CARBON STEEL REBARS IN HIGH PERFORMANCE CONCRETE.
Creator
Rosa-Pagan, Angel R., Presuel-Moreno, Francisco, Florida Atlantic University, Department of Ocean and Mechanical Engineering, College of Engineering and Computer Science
Abstract/Description
A significant amount of reinforced concrete structures in the USA are reaching the design life span of 50 years. Degradation of these infrastructure due to corrosion presents an economical, safety and quality of life challenge for our society. Being able to study and determine the conditions of our infrastructure, perform maintenance before failure and predict failure before occurrence has become critical for our society and our way of life. This study was performed to add to existing...
Show moreA significant amount of reinforced concrete structures in the USA are reaching the design life span of 50 years. Degradation of these infrastructure due to corrosion presents an economical, safety and quality of life challenge for our society. Being able to study and determine the conditions of our infrastructure, perform maintenance before failure and predict failure before occurrence has become critical for our society and our way of life. This study was performed to add to existing research in the understanding of the relationships between the corrosion current of the embedded carbon steel rebars in reinforced concrete, rebar mass loss due to corrosion and the degradation of the mechanical properties of the carbon steel embedded in high performance concrete structures. The study also aimed to study the influence of different independent variables such as the chloride solution reservoir size and the concrete composition of the prepared specimens for the study. Specimens for the study were prepared by embedding three carbon steel size #4 rebars in blocks of high performing concrete with different admixture to enhance their performance against corrosion. To initiate corrosion specimens were exposed to accelerated chloride transport method (electromigration). To accelerate corrosion some samples were selected for anodic polarization and additional electromigration. After corrosion initiation, the rebars Open Circuit Potential (OCP) and corrosion current (Icorr) were periodically measured using a galvanostat device from April 2017 to August 2021. The OCP average values showed that all the rebars considered in this study were in active corrosion. Faraday’s law was used to determine the rebar calculated mass loss from the measured corrosion current and the elapse time between measurements. The rebar mass loss was in turn used to model the loss of the physical properties of the rebar (yield strength, ultimate strength, and ultimate strain) using (Vanama & Ramakrishnan, 2020) model. Analysis of these parameters results showed a direct relationship between the measured corrosion current and the calculated mass loss of the corroding rebar. The study also showed a direct relationship between the calculated mass loss of the corroding rebar and the degradation of the physical properties of the rebar.
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Date Issued
2021
PURL
http://purl.flvc.org/fau/fd/FA00013843
Subject Headings
Corrosion, Reinforced concrete--Deterioration, Carbon steel, High strength concrete
Format
Document (PDF)
Bulk diffusion of high performance concrete specimens exposed to different levels of sodium chloride and seawater
Title
Bulk diffusion of high performance concrete specimens exposed to different levels of sodium chloride and seawater.
Creator
Arias, Wendy J., Presuel-Moreno, Francisco, Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description
The purpose of this study was to investigate the performance to chloride penetration of specimens made with three base compositions (three different supplementary cementitious materials) and water to cementitious ratios of 0.35, 0.41, or 0.47. The specimens were subjected to bulk diffusion test or full immersion. The mixes were exposed to 0.1 M, 0.6 M, or 2.8 M sodium chloride solution for different periods of time. Also, partially immersed specimens were exposed to indoor and outdoor...
Show moreThe purpose of this study was to investigate the performance to chloride penetration of specimens made with three base compositions (three different supplementary cementitious materials) and water to cementitious ratios of 0.35, 0.41, or 0.47. The specimens were subjected to bulk diffusion test or full immersion. The mixes were exposed to 0.1 M, 0.6 M, or 2.8 M sodium chloride solution for different periods of time. Also, partially immersed specimens were exposed to indoor and outdoor exposures (tidal, splash, barge). Chloride concentration profiles were obtained and the apparent diffusion coefficient was calculated. The skin effect was found only on some chloride profiles exposed to 0.1 M sodium chloride solution. The chloride binding capacity was calculated; specimens with 20% Fly Ash and 8% Silica Fume had the highest binding capacity (70.99%). The apparent diffusivity coefficient was found to be dependent on the curing regime as well as the water to cement ratio. The correlation between effective resistivity and apparent diffusion coefficient was determined.
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Date Issued
2014
PURL
http://purl.flvc.org/fau/fd/FA00004076, http://purl.flvc.org/fau/fd/FA00004076
Subject Headings
Bulk solids flow, Concrete -- Corrosion, Concrete, Effect of salt on, Reinforced concrete -- Deterioration, Sustainable construction
Format
Document (PDF)
Initiation and propagation of corrosion in dry-cast reinforced concrete ring specimens
Title
Initiation and propagation of corrosion in dry-cast reinforced concrete ring specimens.
Creator
Seo, Bongjoon, Presuel-Moreno, Francisco, Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description
The corrosion propagation stage of D-CRP (types F and C) was tested under immersion in water, high humidity, and covered with wet sand. The half-cell potential, linear polarization test, and electrochemical impedance spectroscopy measurements were performed. Selected specimens were terminated after 300 days of exposure and visually inspected. Based on corrosion potential measurements obtained during the corrosion propagation observation, and calculated corrosion rate based on LPR measurements...
Show moreThe corrosion propagation stage of D-CRP (types F and C) was tested under immersion in water, high humidity, and covered with wet sand. The half-cell potential, linear polarization test, and electrochemical impedance spectroscopy measurements were performed. Selected specimens were terminated after 300 days of exposure and visually inspected. Based on corrosion potential measurements obtained during the corrosion propagation observation, and calculated corrosion rate based on LPR measurements: all specimens were actively corroding. Additionally, EIS-Rc values were calculated for FS, CS and CH specimens. The Rc_EIS were generally greater than Rc_LPR values. EIS spectra for CI and FI specimens usually included mass transport limitations, as these specimens were immersed. Both type of specimens immersed in water (FI and CI), appeared to have higher corrosion rate based on LPR-Rc. However, upon autopsy it was revealed that a more modest amount of corrosion occurred on the reinforcing steel of FI and CI terminated specimens.
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Date Issued
2014
PURL
http://purl.flvc.org/fau/fd/FA00004226, http://purl.flvc.org/fau/fd/FA00004226
Subject Headings
Concrete -- Deterioration, Concrete construction, Corrosion and anti corrosives, Reinforced concrete -- Chemical resistance, Tubular steel structures -- Deterioration
Format
Document (PDF)
Cathodic polarization response of simulated prestressed concrete piles exposed to natural sea water
Title
Cathodic polarization response of simulated prestressed concrete piles exposed to natural sea water.
Creator
Chaix, Olivier., Florida Atlantic University, Hartt, William H.
Abstract/Description
Experiments were conducted to determine the effectiveness of localized cathodic polarization for reducing corrosion of simulated prestressed concrete piles containing admixed calcium chloride and exposed to a simulated sea water tidal cycle. The specimens contained both continuous and segmented steel tendons, the purpose of the latter being to facilitate measurement of cathodic protection current. Conductive rubber in an impressed current system was used as the anode material. The specimens...
Show moreExperiments were conducted to determine the effectiveness of localized cathodic polarization for reducing corrosion of simulated prestressed concrete piles containing admixed calcium chloride and exposed to a simulated sea water tidal cycle. The specimens contained both continuous and segmented steel tendons, the purpose of the latter being to facilitate measurement of cathodic protection current. Conductive rubber in an impressed current system was used as the anode material. The specimens were initially freely corroded and then cathodically polarized at a constant current ranging from 0.5 to 1 mA/m$\sp2$ which corresponded to potentials (current-on) which ranged from $-$0.500 to $-$1.100 V(sce) in the anode region. The magnitude of impressed current and its distribution along the embedded steel was monitored as a function of exposure time, level of polarization and water levels. Current-on and instant-off potential distribution for both the continuous and segmented tendons were also measured. The level of cathodic polarization was assessed as a function of position along the specimens by the depolarization method. The results were evaluated within the context of marine bridge substructure cathodic protection technology.
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Date Issued
1992
PURL
http://purl.flvc.org/fcla/dt/14865
Subject Headings
Corrosion and anti-corrosives, Sea-water corrosion, Offshore structures, Reinforced concrete--Deterioration
Format
Document (PDF)
Effects of High Alkalinity Cements on the Control of Alkali-Silica Reaction for Reinforced Concrete
Title
Effects of High Alkalinity Cements on the Control of Alkali-Silica Reaction for Reinforced Concrete.
Creator
Suarez, Jorge Alejandro, Hartt, William H., Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description
In previous research, cements with high alkali content (EqA 1.0-1.2 percent) extended the corrosion initiation time of reinforcing steel in concrete. During this study, laboratory tests were performed to determine the suitability of high alkalinity cements to improve concrete durability without modifying physical properties and to control the risk of alkali-aggregate reaction (AAR). A mix design for the FOOT-Class V concrete served as base material for this study. On a cubic meter basis the...
Show moreIn previous research, cements with high alkali content (EqA 1.0-1.2 percent) extended the corrosion initiation time of reinforcing steel in concrete. During this study, laboratory tests were performed to determine the suitability of high alkalinity cements to improve concrete durability without modifying physical properties and to control the risk of alkali-aggregate reaction (AAR). A mix design for the FOOT-Class V concrete served as base material for this study. On a cubic meter basis the cementitious material in this concrete included 363 kg of Type l/ll Portland cement and 83 kg of Class F fly ash. The water-to-cementitious material ratio of the concrete was 0.40. The fine aggregate used in the experimental concretes was quartz sand from a Florida source with no history of alkali-silica reactivity (ASR) susceptibility. A number of cement alkali contents were prepared by different additions of sodium hydroxide to the concrete mix (3.42 - 4.57 kglm\ in some cases, and by using different cements in others. Thus, effects on concrete susceptibility to ASR, electrical resistivity, and strength were studied. Pore water alkalinity was measured by ex-situ leaching and pore water extraction methods. It was concluded that leaching procedures were not appropriate to determine concrete pore water alkalinity in the presence of fly ash. Results suggested that it is feasible to use high alkali cement without the risk of ASR or the loss of strength for two of the seven coarse aggregates studied, given that supplementary cementitious materials and lithium nitrate admixtures are utilized. Criteria for qualification of a concrete as being ASR resistant was based on dimensional stability (less than 0.01% average specimen length change) and the absence of cracking over the one and two year exposure periods according to ASTM Cl293. Based on the fundamentals of the electric double layer theory, the incidence of bivalent cations adjacent to the surface of cement hydrates and reactive silica particles was proposed to provide an explanation for the effects of alkali addition on the electrical resistivity of concrete and the source of the expansive nature of the ASR gel.
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Date Issued
2006
PURL
http://purl.flvc.org/fau/fd/FA00012578
Subject Headings
Reinforced con crete construction, Concrete--Deterioration, Alkali-aggregate reactions, Silica
Format
Document (PDF)
Corrosion Propagation of Rebar Embedded in High Performance Concrete
Title
Corrosion Propagation of Rebar Embedded in High Performance Concrete.
Creator
Nazim, Manzurul, Presuel-Moreno, Francisco, Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description
The FDOT has been using supplementary cementitious materials while constructing steel reinforced concrete marine bridge structures for over 3 decades. Previous findings indicated that such additions in concrete mix makes the concrete more durable. To better understand corrosion propagation of rebar in high performance concrete: mature concrete samples that were made (2008/2009) with Portland cement, a binary mix, a ternary mix and recently prepared (April 2016 with 50% OPC + 50% slag and 80%...
Show moreThe FDOT has been using supplementary cementitious materials while constructing steel reinforced concrete marine bridge structures for over 3 decades. Previous findings indicated that such additions in concrete mix makes the concrete more durable. To better understand corrosion propagation of rebar in high performance concrete: mature concrete samples that were made (2008/2009) with Portland cement, a binary mix, a ternary mix and recently prepared (April 2016 with 50% OPC + 50% slag and 80% OPC + 20% Fly ash) concrete samples were considered. None of these concretes had any admixed chloride to start with. An accelerated chloride transport process was used to drive chloride ions into the concrete so that chlorides reach and exceed thechloride threshold at the rebar surface and initiate corrosion. Electrochemical measurements were taken at regular intervals (during and after the electro-migration process) to observe the corrosion propagation in each sample.
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Date Issued
2017
PURL
http://purl.flvc.org/fau/fd/FA00004941, http://purl.flvc.org/fau/fd/FA00004941
Subject Headings
Reinforced concrete--Corrosion., Reinforced concrete--Chemical resistance., Reinforced concrete--Deterioration., Concrete--Corrosion., Concrete--Mechanical properties.
Format
Document (PDF)
Correlation of Chloride Diffusivity and Electrical Resistance for Cracked Concrete
Title
Correlation of Chloride Diffusivity and Electrical Resistance for Cracked Concrete.
Creator
Merantus, Stanley W., Reddy, Dronnadula V., Florida Atlantic University, College of Engineering and Computer Science, Department of Civil, Environmental and Geomatics Engineering
Abstract/Description
The durability of Reinforced Concrete (RC) structures in the Marine environment is causing serious concern in the structural infrastructure. Reinforced concrete structures, exposed to aggressive environments, are expected to last with little or no maintenance for long periods of time. However, one of the most serious environmental exposures that causes degradation is Chloride Diffusion, due to shrinkage, atmospheric corrosion, and tide-induced wet and dry conditions at the air-water...
Show moreThe durability of Reinforced Concrete (RC) structures in the Marine environment is causing serious concern in the structural infrastructure. Reinforced concrete structures, exposed to aggressive environments, are expected to last with little or no maintenance for long periods of time. However, one of the most serious environmental exposures that causes degradation is Chloride Diffusion, due to shrinkage, atmospheric corrosion, and tide-induced wet and dry conditions at the air-water interfaces of coastal structures. Therefore, chloride diffusivity, which correlates with the electrical resistivity, has a significant impact on the durability of concrete. Concrete chloride diffusivity has been experimented by multiple agencies and researchers on sound concrete, but there is a considerable need for investigation of the durability of cracked concrete in the marine environment. The two test methods carried out are presented: Standardized American Society for Testing and Materials (ASTM) C1202 for Rapid Chloride Permeability (RCP) and ASTM D257 for Surface Resistivity (SR), and Nordtest (NT) Build 492 for Rapid Chloride Migration (RCM) and Bulk Resistivity (BR) for both sound (uncracked) and cracked (micro and macro) concrete. The limitations of the ASTM method, due to measurements before the steady-state migration is reached, does not account for leakage in cracked concrete, and the heating of the specimen due to higher current that increase the conductivity are indicated. The Rapid Chloride Migration test provides for the non-steady state of diffusion. Again, Bulk Resistivity, in contradistinction to Surface Resistivity is more accurate for cracked concrete. The correlation betweeen RCM-BR are plotted. Chloride Permeability/Migration is an important parameter that governs the Durability of Concrete. The principal contribution is the highlighting of the inadequacy of the current widely used standard ASTM C1202 for diffusivity testing, and the need for revision with further investigation.
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Date Issued
2017
PURL
http://purl.flvc.org/fau/fd/FA00004942, http://purl.flvc.org/fau/fd/FA00004942
Subject Headings
Reinforced concrete--Construction--Corrosion., Reinforced concrete--Deterioration., Concrete--Corrosion., Concrete--Chemical resistance., Chlorides--Environmental aspects., Chlorides--Diffusion rate.
Format
Document (PDF)