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Title: Low velocity impact and compression after impact characterization of woven carbon/vinylester at dry and water saturated conditions.
Creator: Dale, Michael, Acha, Betiana A., Carlson, Lief, Graduate College
Date Issued: 2011-04-08
PURL: http://purl.flvc.org/fcla/dt/3164519
Subject Headings: Polymers, Polymeric composites, Accelerometers
Format: Document (PDF)

Title: Adhesive Joint Analyses Using Ansys CZM Modeling of a Prefabricated Hybrid Concrete-GFRP-CFRP Unit.
Creator: Kabaluk, Maksim, Arockiasamy, Madasamy, Florida Atlantic University, College of Engineering and Computer Science, Department of Civil, Environmental and Geomatics Engineering
Abstract/Description: The present study reviews applications of FRP materials joined by structural adhesives in civil engineering. FE analysis with mix-mode cohesive zone material model (CZM) was used to analyze stresses induced in two structural adhesives joining dissimilar materials (concrete GFRP-CFRP) of the hybrid-composite unit. The predicted failure loads, displacements and deformation by the 3-D non-linear FE analysis in the present study are in good agreement with the experimental results of the hybrid...
Show moreThe present study reviews applications of FRP materials joined by structural adhesives in civil engineering. FE analysis with mix-mode cohesive zone material model (CZM) was used to analyze stresses induced in two structural adhesives joining dissimilar materials (concrete GFRP-CFRP) of the hybrid-composite unit. The predicted failure loads, displacements and deformation by the 3-D non-linear FE analysis in the present study are in good agreement with the experimental results of the hybrid-composite unit reported by Deskovic et al. (1995). The contact analysis revealed a complex 3-D state of stress in the bondlines of both structural adhesives. It is concluded that higher joint strength is expected when a ductile adhesive is used.
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Date Issued: 2019
PURL: http://purl.flvc.org/fau/fd/FA00013222
Subject Headings: Adhesive joints, Fiber reinforced polymers, Composites, Concrete
Format: Document (PDF)

Title: The effects of POSS surface treatment on the interlaminar property of marine composites.
Creator: Powell, Felicia M., Granata, Richard D., Hosur, Mahesh, Mahfuz, Hassan, Graduate College
Date Issued: 2011-04-08
PURL: http://purl.flvc.org/fcla/dt/3164682
Subject Headings: Composite materials --Delamination, Fibrous composites, Polymers --Effect of radiation on
Format: Document (PDF)

Title: Degradation of mechanical properties of vinylester and carbon fiber/vinylester composites due to environmental exposure.
Creator: Figliolini, Alexander M., College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description: An experimental investigation was undertaken to determine the effects of marine environmental exposure on the mechanical properties of vinylester resins (VE510A and VE8084) and carbon fiber/VE510A vinylester composites. The effect of carbon fiber sizing on the composite strengths was also examined. Neat resins were exposed to marine environments until moisture content reached a point of saturation after which they were tested in tension, compression and shear. Compared to the baseline dry...
Show moreAn experimental investigation was undertaken to determine the effects of marine environmental exposure on the mechanical properties of vinylester resins (VE510A and VE8084) and carbon fiber/VE510A vinylester composites. The effect of carbon fiber sizing on the composite strengths was also examined. Neat resins were exposed to marine environments until moisture content reached a point of saturation after which they were tested in tension, compression and shear. Compared to the baseline dry specimens, specimens subjected to moisture showed overall increased ductility and a reduction in strength. Dry and moisture saturated composite specimens were tested in tension and compression in different orientations. Longitudinal specimens were tested in in-plane shear and interlaminar shear. Composites with F-sized carbon fibers displayed overall higher strength than those with G-sized fibers at both dry and moisture saturated conditions. An analysis of moisture absorption of the composites was performed which vii shows that the moisture up-take is dominated by the fiber/matrix region which absorbs up to 90% of the moisture. The composites experienced reduced strength after moisture absorption. The results revealed that the fiber sizing has stronger effect on the fiber/matrix interface dominated strengths than moisture up-take.
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Date Issued: 2011
PURL: http://purl.flvc.org/FAU/3332182
Subject Headings: Composite materials, Mechanical properties, Polymers, Deterioration, FIbrous composites, Graphite fibers
Format: Document (PDF)

Title: Degradation of the composite fiber/matrix interface in marine environment.
Creator: Farooq, Muhammad Umar., College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description: Durability of the composite materials in marine environments has been investigated experimentally and with analytical and numerical methods. The main focus of this study is on the integrity of the fiber/matrix interface under seawater exposure. A single-fiber compression test specimen called the Outwater-Murphy (OM) test has been analyzed using mechanics of materials principles and linear elastic fracture mechanics. Sizing of the OM specimen was conducted so that debonding of the fiber from...
Show moreDurability of the composite materials in marine environments has been investigated experimentally and with analytical and numerical methods. The main focus of this study is on the integrity of the fiber/matrix interface under seawater exposure. A single-fiber compression test specimen called the Outwater-Murphy (OM) test has been analyzed using mechanics of materials principles and linear elastic fracture mechanics. Sizing of the OM specimen was conducted so that debonding of the fiber from the interface should be achieved prior to yielding of the matrix and global instability failure. Stress analysis of the OM specimen has been conducted from theory of elasticity and finite element analysis. A superelement technique was developed for detailed analysis of the stress state at the fiber/matrix interface. The interface stress state at the debond site in the OM specimen, i.e. at the hole edge, was identified as biaxial tension at the fiber/matrix interface. Characterization of cure and post-cure of 8084 and 510A vinlyester resins has been performed using cure shrinkage tests based on dynamic mechanical analysis and coated beam experiments. In addition, moisture absorption, swelling and the influence of moisture on the mechanical properties of the resins were determined. Testing of OM specimens consisting of a single carbon or glass fiber embedded in vinylester resin at dry conditions and after seawater exposure revealed that the debond toughness was substantially reduced after exposure of the OM specimen to seawater. C(F) did not debond. Macroscopic carbon/vinylester woven composites where the fibers were sized with F sizing were tested in shear at dry conditions and after four weeks of seawater exposure. The shear strength was very little affected after the short immersion time.
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Date Issued: 2009
PURL: http://purl.flvc.org/FAU/228774
Subject Headings: Fibrous composites, Graphite fibers, Composite materials, Mechanical properties, Polymers, Deterioration
Format: Document (PDF)

Title: Evaluation of Water Degradation ofPolymer Matrix Composites by Micromechanical and Macromechanical Tests.
Creator: Ramirez, Felipe A., Carlsson, Leif A., Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description: Degradation of the critical components of polymer matrix composites in marine environments had been experimentally investigated. Water absorption behavior of neat resin and composite specimens was examined. The tensile strength of fibers was monitored using the single filament test. The mechanical properties of the resins were monitored by tensile, flexure, and dynamic-mechanical tests. In addition, matrix shrinkage during cure and matrix swelling after immersion in water were monitored. The...
Show moreDegradation of the critical components of polymer matrix composites in marine environments had been experimentally investigated. Water absorption behavior of neat resin and composite specimens was examined. The tensile strength of fibers was monitored using the single filament test. The mechanical properties of the resins were monitored by tensile, flexure, and dynamic-mechanical tests. In addition, matrix shrinkage during cure and matrix swelling after immersion in water were monitored. The integrity of the fiber/matrix (F/M) interface of the composite systems was studied using the single fiber fragmentation test (SFFT). Macroscopic composites were examined using transverse tensile and transverse flexure tests to study the influence of the integrity of the matrix and F/M interface on the macroscopic response. In addition, for characterization of F/M debonding in the SFFT, a fracture mechanics model and modified test procedure were developed.
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Date Issued: 2008
PURL: http://purl.flvc.org/fau/fd/FA00012543
Subject Headings: Composite materials--Mechanical properties, Polymeric composites--Testing, Fibrous composites--Testing, Polymers--Deterioration
Format: Document (PDF)

Title: Investigation of nanoscale reinforcement into textile polymers.
Creator: Khan, Mujibur Rahman., College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description: A dual inclusion strategy for textile polymers has been investigated to increase elastic energy storage capacity of fibers used in high velocity impact applications. Commercial fibers such as Spectra and Dyneema are made from ultra high molecular weight polyethylene (UHMWPE). Dynamic elastic energy of these fibers is still low therefore limiting their wholesale application without a secondary metallic or ceramic component. The idea in this investigation is to develop methodologies so that the...
Show moreA dual inclusion strategy for textile polymers has been investigated to increase elastic energy storage capacity of fibers used in high velocity impact applications. Commercial fibers such as Spectra and Dyneema are made from ultra high molecular weight polyethylene (UHMWPE). Dynamic elastic energy of these fibers is still low therefore limiting their wholesale application without a secondary metallic or ceramic component. The idea in this investigation is to develop methodologies so that the elastic energy of polyethylene based fibers can be increased by several folds. This would allow manufacturing of an all-fabric system for high impact applications. The dual inclusion consists of a polymer phase and a nanoscale inorganic phase to polyethylene. The polymer phase was nylon-6 and the inorganic phase was carbon nanotubes (CNTs). Nylon-6 was blended as a minor phase into UHMWPE and was chosen because of its large fracture strain - almost one order higher than that of UHMWPE. On the other hand, CNTs with their very high strength, modulus, and aspect ratio, contributed to sharing of load and sliding of polymer interfaces as they aligned during extrusion and strain hardening processes. A solution spinning process was developed to produce UHMWPE filaments reinforced with CNTs and nylon-6. The procedure involved dispersing of CNTs into paraffin oil through sonication followed by dissolving polymers into paraffin-CNT solution using a homogenizer. The admixture was fed into a single screw extruder for melt mixing and extrusion through an orifice. The extrudate was rinsed via a hexane bath, stabilized through a heater, and then drawn into a filament winder with controlled stretching. In the next step, the as produced filaments were strain-hardened through repeated loading unloading cycles under tension., Neat and reinforced filaments were characterized through DSC (Differential Scanning Calorimetry), XRD (X-ray Diffraction), Raman Spectroscopy, SEM (Scanning Electron Microscope), and mechanical tests. Phenomenal improvement in properties was found; modulus, strength, fracture strain, and elastic energy increased by 219%, 100%, 107% and 88%, respectively before strain hardening. Once strain hardened the strength, modulus and elastic energy increased by almost one order of magnitude. Source of these improvements were traced to increase in crystallinity and rate of crystallization, formation of microdroplets as a minor phase, sliding between minor and major phases, coating of nanotubes with polymer and alignment of nanotubes.
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Date Issued: 2010
PURL: http://purl.flvc.org/FAU/2976443
Subject Headings: Nanostructured materials, Composite materials, Textile fibers, Synthetic, Polymers, Electric properties
Format: Document (PDF)

Title: Electrochemical impedance spectroscopy to monitor degradation of carbon fiber reinforced polymer composites subjected to simulated ocean environment.
Creator: Ahmed, Mohammad Mesbahuddin., Florida Atlantic University, Lipka, Stephen M.
Abstract/Description: This research evaluated the applicability of electrochemical impedance spectroscopy (EIS) as a non-destructive technique to predict and characterize the degradation of carbon fiber reinforced polymer (CFRP) composites exposed to aqueous environments at ambient and 6.2 $\pm$ 0.3 MPa. Changes in EIS data were related to water uptake into the composite material as a function of exposure time. Electrochemically induced damage (both anodic and cathodic) were also evaluated using impedance...
Show moreThis research evaluated the applicability of electrochemical impedance spectroscopy (EIS) as a non-destructive technique to predict and characterize the degradation of carbon fiber reinforced polymer (CFRP) composites exposed to aqueous environments at ambient and 6.2 $\pm$ 0.3 MPa. Changes in EIS data were related to water uptake into the composite material as a function of exposure time. Electrochemically induced damage (both anodic and cathodic) were also evaluated using impedance measurements. Three point flexure tests with concurrent EIS measurements were employed to study the effect of stresses on water uptake and mechanical degradation. Visual observation of the extent of damage (i.e., fiber-matrix debonding) was made using scanning electron microscopy (SEM) and correlated with EIS observation.
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Date Issued: 1993
PURL: http://purl.flvc.org/fcla/dt/14962
Subject Headings: Polymers--Deterioration, Composite materials--Environmental aspects, Carbon fibers, Polymeric composites, Spectrum analysis
Format: Document (PDF)

Title: Transport of seawater and its influence on the transverse tensile strength of unidirectional composite materials.
Creator: Fichera, Maryann, Carlsson, Leif A., Florida Atlantic University, College of Engineering and Computer Science, Department of Ocean and Mechanical Engineering
Abstract/Description: The objective of this research was to characterize the seawater transport and its effect on the transverse tensile strength of a carbon/vinylester composite. The moisture contents of neat vinylester and unidirectional carbon/vinylester composite panels immersed in seawater were monitored until saturation. A model for moisture up-take was developed based on superposition of Fickian diffusion, and Darcy’s law for capillary transport of water. Both the predicted and measured saturation times...
Show moreThe objective of this research was to characterize the seawater transport and its effect on the transverse tensile strength of a carbon/vinylester composite. The moisture contents of neat vinylester and unidirectional carbon/vinylester composite panels immersed in seawater were monitored until saturation. A model for moisture up-take was developed based on superposition of Fickian diffusion, and Darcy’s law for capillary transport of water. Both the predicted and measured saturation times increased with increasing panel size, however the diffusion model predicts much longer times while the capillary model predicts shorter time than observed experimentally. It was also found that the saturation moisture content decreased with increasing panel size. Testing of macroscopic and miniature composite transverse tensile specimens, and SEM failure inspection revealed more fiber/matrix debonding in the seawater saturated composite than the dry composite, consistent with a slightly reduced transverse tensile strength.
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Date Issued: 2015
PURL: http://purl.flvc.org/fau/fd/FA00004368, http://purl.flvc.org/fau/fd/FA00004368
Subject Headings: Composite materials -- Deterioration, Composite materials -- Effect of environment on, Engineering design, Marine engineering, Polymers -- Permeability, Polymetric composites -- Deterioration
Format: Document (PDF)

Title: Strength and durability of fly ash-based fiber-reinforced geopolymer concrete in a simulated marine environment.
Creator: Martinez Rivera, Francisco Javier, Sobhan, Khaled, College of Engineering and Computer Science, Department of Civil, Environmental and Geomatics Engineering
Abstract/Description: This research is aimed at investigating the corrosion durability of polyolefin fiber-reinforced fly ash-based geopolymer structural concrete (hereafter referred to as GPC, in contradistinction to unreinforced geopolymer concrete referred to as simply geopolymer concrete), where cement is completely replaced by fly ash, that is activated by alkalis, sodium hydroxide and sodium silicate. The durability in a marine environment is tested through an electrochemical method for accelerated corrosion...
Show moreThis research is aimed at investigating the corrosion durability of polyolefin fiber-reinforced fly ash-based geopolymer structural concrete (hereafter referred to as GPC, in contradistinction to unreinforced geopolymer concrete referred to as simply geopolymer concrete), where cement is completely replaced by fly ash, that is activated by alkalis, sodium hydroxide and sodium silicate. The durability in a marine environment is tested through an electrochemical method for accelerated corrosion. The GPC achieved compressive strengths in excess of 6,000 psi. Fiber reinforced beams contained polyolefin fibers in the amounts of 0.1%, 0.3%, and 0.5% by volume. After being subjected to corrosion damage, the GPC beams were analyzed through a method of crack scoring, steel mass loss, and residual flexural strength testing. Fiber reinforced GPC beams showed greater resistance to corrosion damage with higher residual flexural strength. This makes GPC an attractive material for use in submerged marine structures.
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Date Issued: 2013
PURL: http://purl.flvc.org/fau/fd/FA0004037
Subject Headings: Concrete mixing -- Quality control, Green chemistry, Polymer composites, Reinforced concrete -- Corrosion -- Testing, Reinforced concrete construction
Format: Document (PDF)

Title: Synthesis and photophysical measurements of a series of lanthanide-benzenedicarboxylate coordination polymers.
Creator: Clark, Jessica Montressa., Charles E. Schmidt College of Science, Department of Chemistry and Biochemistry
Abstract/Description: Within solid-state chemistry, coordination polymers have gained interest for use in various applications such as sensing, catalysis, display technology, hydrogen storage, etc. The use of lanthanide ions in these materials provides a mean of exploring how structure may affect luminescence efficiency. In this study, the photophysics of several lanthanide benzenecarboxylates was studied. This data combined with data from other coordination polymers created in our lab indicate that the...
Show moreWithin solid-state chemistry, coordination polymers have gained interest for use in various applications such as sensing, catalysis, display technology, hydrogen storage, etc. The use of lanthanide ions in these materials provides a mean of exploring how structure may affect luminescence efficiency. In this study, the photophysics of several lanthanide benzenecarboxylates was studied. This data combined with data from other coordination polymers created in our lab indicate that the established guidelines for producing highly efficient materials may not correlate directly from solution to the solid state and that structure may also play a role.
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Date Issued: 2013
PURL: http://purl.flvc.org/fcla/dt/3362332
Subject Headings: Rare earth metals catalysts, Metallic composites, Speciation, Lanthanide shift reagents, Organic compounds, Synthesis, Polymers, Biotechnology
Format: Document (PDF)

Title: Experimental evaluation of the durability of fly ash-based geopolymer concrete in the marine environment.
Creator: Edouard, Jean-Baptiste., College of Engineering and Computer Science, Department of Civil, Environmental and Geomatics Engineering
Abstract/Description: The construction industry is increasingly turning to the use of environmentally friendly materials in order to meet the sustainable aspect required by modern infrastructures. Consequently, for the last two decades, the expansion of this concept, and the increasing global warming have raised concerns on the extensive use of Portland cement due to the high amount of carbon dioxide gas associated with its production. The development of geopolymer concretes offers promising signs for a change in...
Show moreThe construction industry is increasingly turning to the use of environmentally friendly materials in order to meet the sustainable aspect required by modern infrastructures. Consequently, for the last two decades, the expansion of this concept, and the increasing global warming have raised concerns on the extensive use of Portland cement due to the high amount of carbon dioxide gas associated with its production. The development of geopolymer concretes offers promising signs for a change in the way of producing concrete. However, to seriously consider geopolymer binders as an alternative to ordinary Portland cement, the durability of this new material should be evaluated in any comparative analysis. The main purpose of this study was to evaluate the durability characteristics of low calcium fly ash-based geopolymer concretes subjected to the marine environment, compared to ordinary Portland cement concrete with similar exposure. To achieve this goal, 8 molar geopolymer, 14 molar geopolymer and ordinary Portland cement concrete mixes were prepared and tested for exposure in seawater. Compressive strengths in the range of 2900 to 8700 psi (20-60 MPa) were obtained. The corrosion resistance performance of steel-reinforced concrete beams, made of these mixes, was also studied, using an accelerated electrochemical method, with submergence in salt water. The test results indicated that the geopolymer concrete showed excellent resistance to chloride attack, with longer time to corrosion cracking, compared to ordinary Portland cement concrete.
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Date Issued: 2011
PURL: http://purl.flvc.org/FAU/3170960
Subject Headings: Reinforced concrete, Corrosion, Testing, Reinforced concrete construction, Concrete, Mixing, Quality control, Environmental chemistry, Industrial applications, Polymer composites
Format: Document (PDF)

Title: Initial evaluation of organotin monomers and polymers as potential anticancer agents.
Creator: Doucette, Randy D., Florida Atlantic University, Louda, Deborah W.
Abstract/Description: A large number of metal-containing compounds show significant activity against cancer cells and incorporating a metal into a polymer offers several possible advantages. Compounds of the type R2SnCl2 (R = methyl, ethyl, propyl, butyl, t-butyl, octyl and phenyl) were tested for the ability to inhibit the growth of Balb 3T3 mouse fibroblast cells and CAOV3 human ovarian carcinoma cells. Polymers of 2-chloro-1,4-benzenediamine and the same organotin dichloride were synthesized and tested as well....
Show moreA large number of metal-containing compounds show significant activity against cancer cells and incorporating a metal into a polymer offers several possible advantages. Compounds of the type R2SnCl2 (R = methyl, ethyl, propyl, butyl, t-butyl, octyl and phenyl) were tested for the ability to inhibit the growth of Balb 3T3 mouse fibroblast cells and CAOV3 human ovarian carcinoma cells. Polymers of 2-chloro-1,4-benzenediamine and the same organotin dichloride were synthesized and tested as well. For both monomers and polymers, the pattern of growth inhibition relative to the R group was butyl > propyl = t-butyl = octyl = phenyl > ethyl > methyl. This and other aspects of the structure-activity relationship of the monomers and polymers were examined.
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Date Issued: 2006
PURL: http://purl.flvc.org/fcla/dt/13410
Subject Headings: Apoptosis--Molecular aspects, Polymeric composites, Organometallic compounds, Cancer--Molecular aspects, Antineoplastic agents--Testing, Polymers in medicine
Format: Document (PDF)

FAU Theses and Dissertations (11)	+ -
FAU Graduate Student Research (2)	+ -

Polymers (5)	+ -
Composite materials (3)	+ -
Polymeric composites (3)	+ -
Concrete (2)	+ -
Deterioration (2)	+ -

Fibrous composites (2)	+ -
Graphite fibers (2)	+ -
Mechanical properties (2)	+ -
Polymer composites (2)	+ -
Polymers--Deterioration (2)	+ -
Reinforced concrete construction (2)	+ -
Accelerometers (1)	+ -
Adhesive joints (1)	+ -
Antineoplastic agents--Testing (1)	+ -
Apoptosis--Molecular aspects (1)	+ -
Biotechnology (1)	+ -
Cancer--Molecular aspects (1)	+ -
Carbon fibers (1)	+ -
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Composite materials -- Effect of environment on (1)	+ -
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Composite materials--Environmental aspects (1)	+ -
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Environmental chemistry (1)	+ -
FIbrous composites (1)	+ -

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abstract (2)	+ -

College of Engineering and Computer Science (8)	+ -
Department of Ocean and Mechanical Engineering (5)	+ -
Florida Atlantic University (5)	+ -
Department of Civil, Environmental and Geomatics Engineering (3)	+ -
Carlsson, Leif A. (2)	+ -

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