Current Search: Loitz, Joseph William (x)
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Title
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Isolation and characterization of chlorophyll and carotenoids in Florida Bay: Phytoplankton, microphytobenthos and sediments.
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Creator
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Loitz, Joseph William, Florida Atlantic University, Louda, J. William
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Abstract/Description
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An analysis of the waters, microphytobenthos, and carbonate marl sediments of Florida Bay was performed using ion-paired RP-HPLC-PDA for chemotaxonomic characterization of past and present photoautotrophic, communities. Application of regression formulae was determined to be applicable for the waters, microphytobenthos, and surficial sediments (0--5 cm) of Florida Bay using chemotaxonomic principles. Loss of chemotaxonomically important pigments with depth prevented similar application in...
Show moreAn analysis of the waters, microphytobenthos, and carbonate marl sediments of Florida Bay was performed using ion-paired RP-HPLC-PDA for chemotaxonomic characterization of past and present photoautotrophic, communities. Application of regression formulae was determined to be applicable for the waters, microphytobenthos, and surficial sediments (0--5 cm) of Florida Bay using chemotaxonomic principles. Loss of chemotaxonomically important pigments with depth prevented similar application in deeper strata (>5 cm), however, past oxic and anoxic trends could be determined. Sedimentary alteration of pigments are characterized by: rapid conversion of chlorophylls-alpha and bacteriochlorophylls-alpha to their respective pheophytins-alpha, creation of a 'carotenoid diol-cluster', equilibrium isomerization of beta-carotene (15-cis and trans), and rapid conversion of pyropheophorbide-alpha to cyclopheophorbide-alpha. An abundant presence of pyropheophorbide-alpha steryl/hopanoid esters and an unusual relationship between organic carbon and water content providing the sediments with polymeric characteristics were also found.
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Date Issued
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1999
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PURL
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http://purl.flvc.org/fcla/dt/15734
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Subject Headings
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Marine sediments--Florida--Florida Bay, Carotenoids--Analysis, Chlorophyll--Analysis
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Format
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Document (PDF)
