You are here

INVESTIGATING THE POTENTIAL OF AMINE-GRAFTED SILICA MATERIALS FOR SIMULTANEOUS REMOVAL OF CARBON DIOXIDE, WATER VAPOR, AND HYDROGEN SULFIDE FROM LANDFILL GAS

Download pdf | Full Screen View

Date Issued:
2023
Abstract/Description:
Amine-grafted silica (i.e., aminosilicas) was investigated for single-stage landfill gas purification via simultaneous removal of CO2, H2S, and water vapor. Aminosilica materials were synthesized by covalent triamine grafting onto mesoporous silica with custom amounts of water and amine. Screening adsorption experiments were completed in dry 30 vol.% CO2 in N2 at 40 °C and assessed using thermogravimetric analysis. Materials with equilibrium CO2 uptakes greater than 1.5 mmol/g were chosen for CO2 adsorption kinetics assessments. The highest-performing aminosilica achieved fast CO2 adsorption by reaching 80% of its equilibrium uptake in one minute. This material also maintained 100% of its initial CO2 uptake when subjected to rigorous 100-cycle testing. It underwent column-breakthrough tests in the presence of different dry and humid gas streams containing CO2, H2S, and water vapor, and achieved concurrent and complete (100%) removal of all target impurities. The results suggest that aminosilicas can purify landfill gas in a single stage.
Title: INVESTIGATING THE POTENTIAL OF AMINE-GRAFTED SILICA MATERIALS FOR SIMULTANEOUS REMOVAL OF CARBON DIOXIDE, WATER VAPOR, AND HYDROGEN SULFIDE FROM LANDFILL GAS.
28 views
13 downloads
Name(s): Lam, Dung , author
Lashaki, Masoud Jahandar, Thesis advisor
Florida Atlantic University, Degree grantor
Department of Civil, Environmental and Geomatics Engineering
College of Engineering and Computer Science
Type of Resource: text
Genre: Electronic Thesis Or Dissertation
Date Created: 2023
Date Issued: 2023
Publisher: Florida Atlantic University
Place of Publication: Boca Raton, Fla.
Physical Form: application/pdf
Extent: 85 p.
Language(s): English
Abstract/Description: Amine-grafted silica (i.e., aminosilicas) was investigated for single-stage landfill gas purification via simultaneous removal of CO2, H2S, and water vapor. Aminosilica materials were synthesized by covalent triamine grafting onto mesoporous silica with custom amounts of water and amine. Screening adsorption experiments were completed in dry 30 vol.% CO2 in N2 at 40 °C and assessed using thermogravimetric analysis. Materials with equilibrium CO2 uptakes greater than 1.5 mmol/g were chosen for CO2 adsorption kinetics assessments. The highest-performing aminosilica achieved fast CO2 adsorption by reaching 80% of its equilibrium uptake in one minute. This material also maintained 100% of its initial CO2 uptake when subjected to rigorous 100-cycle testing. It underwent column-breakthrough tests in the presence of different dry and humid gas streams containing CO2, H2S, and water vapor, and achieved concurrent and complete (100%) removal of all target impurities. The results suggest that aminosilicas can purify landfill gas in a single stage.
Identifier: FA00014182 (IID)
Degree granted: Thesis (MS)--Florida Atlantic University, 2023.
Collection: FAU Electronic Theses and Dissertations Collection
Note(s): Includes bibliography.
Subject(s): Gases--Purification
Landfill gases--Purification
Persistent Link to This Record: http://purl.flvc.org/fau/fd/FA00014182
Use and Reproduction: Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
Host Institution: FAU
Is Part of Series: Florida Atlantic University Digital Library Collections.