You are here
pH determination of concrete pore water by a leaching technique for various concrete mixtures
- Date Issued:
- 1996
- Summary:
- A pH determination technique of concrete pore water by means of leaching OH- ions from powdered samples was developed. This method was then evaluated in terms of sample size, extent of dilution, leaching period, the type of leaching, calcium hydroxide error, and titration scatter. Based upon variations of the above parameters it was concluded that a maximum amount of hydroxide ions was released into solution for samples with the smallest particle size within a 24 hours static leaching period. A 50ml dilution volume proved optimum with regard to filtration and titration. Under the above circumstances calcium hydroxide dissolution did not seem to pose a significant source of error. Furthermore, repeatability of the measurements was good and titration scatter was determined to be about 0.05 pH units. This method was used to determine the pH of samples containing different amounts of fly ash or silica fume additions as well as plain cement (control) samples. A drop in OH- concentration, that is pH, was detected with increasing pozzolanic addition. The results are discussed with the context of the degree of corrosion mitigation afforded by these pozzolans.
Title: | pH determination of concrete pore water by a leaching technique for various concrete mixtures. |
![]() ![]() |
---|---|---|
Name(s): |
Sitton, Izic. Florida Atlantic University, Degree grantor Hartt, William H., Thesis advisor College of Engineering and Computer Science Department of Ocean and Mechanical Engineering |
|
Type of Resource: | text | |
Genre: | Electronic Thesis Or Dissertation | |
Issuance: | monographic | |
Date Issued: | 1996 | |
Publisher: | Florida Atlantic University | |
Place of Publication: | Boca Raton, Fla. | |
Physical Form: | application/pdf | |
Extent: | 135 p. | |
Language(s): | English | |
Summary: | A pH determination technique of concrete pore water by means of leaching OH- ions from powdered samples was developed. This method was then evaluated in terms of sample size, extent of dilution, leaching period, the type of leaching, calcium hydroxide error, and titration scatter. Based upon variations of the above parameters it was concluded that a maximum amount of hydroxide ions was released into solution for samples with the smallest particle size within a 24 hours static leaching period. A 50ml dilution volume proved optimum with regard to filtration and titration. Under the above circumstances calcium hydroxide dissolution did not seem to pose a significant source of error. Furthermore, repeatability of the measurements was good and titration scatter was determined to be about 0.05 pH units. This method was used to determine the pH of samples containing different amounts of fly ash or silica fume additions as well as plain cement (control) samples. A drop in OH- concentration, that is pH, was detected with increasing pozzolanic addition. The results are discussed with the context of the degree of corrosion mitigation afforded by these pozzolans. | |
Identifier: | 9780591177701 (isbn), 15364 (digitool), FADT15364 (IID), fau:12131 (fedora) | |
Collection: | FAU Electronic Theses and Dissertations Collection | |
Note(s): |
College of Engineering and Computer Science Thesis (M.S.)--Florida Atlantic University, 1996. |
|
Subject(s): |
Concrete--Corrosion Seawater corrosion Concrete--Testing Leaching |
|
Held by: | Florida Atlantic University Libraries | |
Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/15364 | |
Sublocation: | Digital Library | |
Use and Reproduction: | Copyright © is held by the author, with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder. | |
Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
Host Institution: | FAU | |
Is Part of Series: | Florida Atlantic University Digital Library Collections. |