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Electronic energy levels of some tetragonal copper ion and chromium ion complexes

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Date Issued:
1996
Summary:
The electronic spectrum of Cu(II)(L-His)2 has been measured in the visible-near IR and UV regions. By assigning ligand field bands and by fitting the band maxima with calculated energies using angular overlap model, the structure of the complex has been deduced to be five-coordinate C4v1 The observed bands in the UV spectrum have been assigned as due to ligand-to-metal charge transfer transitions. Electronic spectra of Cu(II)(diphenylcarbazide)2 and Cr(II)(diphenylcarbazone)(H2O)4 complexes have also been measured. By interpretation of the ligand field bands in these spectra, tentative structures of these complexes in solution have been proposed.
Title: Electronic energy levels of some tetragonal copper ion and chromium ion complexes.
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Name(s): Davari, Mortaza.
Florida Atlantic University, Degree grantor
Perumareddi, Jayarama R., Thesis advisor
Type of Resource: text
Genre: Electronic Thesis Or Dissertation
Issuance: monographic
Date Issued: 1996
Publisher: Florida Atlantic University
Place of Publication: Boca Raton, Fla.
Physical Form: application/pdf
Extent: 84 p.
Language(s): English
Summary: The electronic spectrum of Cu(II)(L-His)2 has been measured in the visible-near IR and UV regions. By assigning ligand field bands and by fitting the band maxima with calculated energies using angular overlap model, the structure of the complex has been deduced to be five-coordinate C4v1 The observed bands in the UV spectrum have been assigned as due to ligand-to-metal charge transfer transitions. Electronic spectra of Cu(II)(diphenylcarbazide)2 and Cr(II)(diphenylcarbazone)(H2O)4 complexes have also been measured. By interpretation of the ligand field bands in these spectra, tentative structures of these complexes in solution have been proposed.
Identifier: 15318 (digitool), FADT15318 (IID), fau:12088 (fedora)
Collection: FAU Electronic Theses and Dissertations Collection
Note(s): Thesis (M.S.)--Florida Atlantic University, 1996.
Charles E. Schmidt College of Science
Subject(s): Copper compounds
Chromium compounds
Electron spectroscopy
Held by: Florida Atlantic University Libraries
Persistent Link to This Record: http://purl.flvc.org/fcla/dt/15318
Sublocation: Digital Library
Use and Reproduction: Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
Use and Reproduction: http://rightsstatements.org/vocab/InC/1.0/
Host Institution: FAU
Is Part of Series: Florida Atlantic University Digital Library Collections.