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Electronic energy levels of some tetragonal copper ion and chromium ion complexes
- Date Issued:
- 1996
- Summary:
- The electronic spectrum of Cu(II)(L-His)2 has been measured in the visible-near IR and UV regions. By assigning ligand field bands and by fitting the band maxima with calculated energies using angular overlap model, the structure of the complex has been deduced to be five-coordinate C4v1 The observed bands in the UV spectrum have been assigned as due to ligand-to-metal charge transfer transitions. Electronic spectra of Cu(II)(diphenylcarbazide)2 and Cr(II)(diphenylcarbazone)(H2O)4 complexes have also been measured. By interpretation of the ligand field bands in these spectra, tentative structures of these complexes in solution have been proposed.
Title: | Electronic energy levels of some tetragonal copper ion and chromium ion complexes. |
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Name(s): |
Davari, Mortaza. Florida Atlantic University, Degree grantor Perumareddi, Jayarama R., Thesis advisor |
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Type of Resource: | text | |
Genre: | Electronic Thesis Or Dissertation | |
Issuance: | monographic | |
Date Issued: | 1996 | |
Publisher: | Florida Atlantic University | |
Place of Publication: | Boca Raton, Fla. | |
Physical Form: | application/pdf | |
Extent: | 84 p. | |
Language(s): | English | |
Summary: | The electronic spectrum of Cu(II)(L-His)2 has been measured in the visible-near IR and UV regions. By assigning ligand field bands and by fitting the band maxima with calculated energies using angular overlap model, the structure of the complex has been deduced to be five-coordinate C4v1 The observed bands in the UV spectrum have been assigned as due to ligand-to-metal charge transfer transitions. Electronic spectra of Cu(II)(diphenylcarbazide)2 and Cr(II)(diphenylcarbazone)(H2O)4 complexes have also been measured. By interpretation of the ligand field bands in these spectra, tentative structures of these complexes in solution have been proposed. | |
Identifier: | 15318 (digitool), FADT15318 (IID), fau:12088 (fedora) | |
Collection: | FAU Electronic Theses and Dissertations Collection | |
Note(s): |
Thesis (M.S.)--Florida Atlantic University, 1996. Charles E. Schmidt College of Science |
|
Subject(s): |
Copper compounds Chromium compounds Electron spectroscopy |
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Held by: | Florida Atlantic University Libraries | |
Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/15318 | |
Sublocation: | Digital Library | |
Use and Reproduction: | Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder. | |
Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
Host Institution: | FAU | |
Is Part of Series: | Florida Atlantic University Digital Library Collections. |