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synthesis of bis(dimolybdenum)-1,3,5,7-tetrakis(2-pyridylimino) benzodipyrrole as a precursor for an inorganic, quadruple bond containing polymer
| Title: | The synthesis of bis(dimolybdenum)-1,3,5,7-tetrakis(2-pyridylimino) benzodipyrrole as a precursor for an inorganic, quadruple bond containing polymer. |
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| Name(s): |
Kavanaugh, David John Florida Atlantic University, Degree grantor Baird, Donald M., Thesis advisor Charles E. Schmidt College of Science Department of Chemistry and Biochemistry |
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| Type of Resource: | text | |
| Genre: | Electronic Thesis Or Dissertation | |
| Issuance: | monographic | |
| Date Issued: | 1993 | |
| Publisher: | Florida Atlantic University | |
| Place of Publication: | Boca Raton, FL | |
| Physical Form: | application/pdf | |
| Extent: | 132 p. | |
| Language(s): | English | |
| Summary: | The planar, dinuclear, tridentate ligands, 1,3,5,7-tetrakis(2-pyridylimino)benzodipyrrole (TAII) and 1,3,5,7-tetrakis(4,6-dimethyl-2-pyridylimino)benzodipyrrole (DiMeTAII) were synthesized and characterized as were all intermediates characterized by both infrared and 1H-NMR spectra. Evidence is presented for the formation of Mo4(OAc)6-(DiMeTAII) (I), the dinuclear analog of Mo2(OAc)3-BAII using UV/Vis to show the delta--->delta* transition typical of the quadruple bond and for the determination of percent molybdenum which is consistent with the proposed structure. A review of recent studies into the field of quadruply bonded metal containing polymers will be discussed along with application of compound (I) in this field. | |
| Identifier: | 14950 (digitool), FADT14950 (IID), fau:11730 (fedora) | |
| Degree granted: | Thesis (M.S.)--Florida Atlantic University, 1993. | |
| Collection: | FAU Electronic Theses and Dissertations Collection | |
| Note(s): | Charles E. Schmidt College of Science | |
| Subject(s): |
Ligands (Biochemistry) Metal-metal bonds Diffusion bonding (Metals) |
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| Held by: | Florida Atlantic University Libraries | |
| Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/14950 | |
| Sublocation: | Digital Library | |
| Use and Reproduction: | Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder. | |
| Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
| Host Institution: | FAU | |
| Is Part of Series: | Florida Atlantic University Digital Library Collections. |
