You are here

Synthesis and characterization of group IVB metallocene materials derived from hematoporphyrin IX

Download pdf | Full Screen View

Date Issued:
1993
Summary:
New organometallic containing materials were synthesized by the reaction of Group IVB metallocene dichlorides of the form Cp2MCl2 where M = Ti, Ar, and Hf with Hematoporphyrin IX using the interfacial condensation polymerization technique. The structural characterization was accomplished using infrared and mass spectroscopy and elemental analysis. The results obtained from these techniques showed the presence of the metal ester and ether bonding as evidence that the reaction occurred. The product derived from titanocene dichloride, 12-A, exhibited growth inhibition characteristics towards the Candid albicans and Staphylococcus aureus microorganisms. From the preliminary metal adsorption studies it was shown that this product also bound nickel ions.
Title: Synthesis and characterization of group IVB metallocene materials derived from hematoporphyrin IX.
112 views
33 downloads
Name(s): Rivalta, Alberto Enrico.
Florida Atlantic University, Degree grantor
Carraher, Charles E.
Haky, Jerome E., Thesis advisor
Type of Resource: text
Genre: Electronic Thesis Or Dissertation
Issuance: monographic
Date Issued: 1993
Publisher: Florida Atlantic University
Place of Publication: Boca Raton, Fla.
Physical Form: application/pdf
Extent: 114 p.
Language(s): English
Summary: New organometallic containing materials were synthesized by the reaction of Group IVB metallocene dichlorides of the form Cp2MCl2 where M = Ti, Ar, and Hf with Hematoporphyrin IX using the interfacial condensation polymerization technique. The structural characterization was accomplished using infrared and mass spectroscopy and elemental analysis. The results obtained from these techniques showed the presence of the metal ester and ether bonding as evidence that the reaction occurred. The product derived from titanocene dichloride, 12-A, exhibited growth inhibition characteristics towards the Candid albicans and Staphylococcus aureus microorganisms. From the preliminary metal adsorption studies it was shown that this product also bound nickel ions.
Identifier: 14940 (digitool), FADT14940 (IID), fau:11720 (fedora)
Note(s): Charles E. Schmidt College of Science
Thesis (M.S.)--Florida Atlantic University, 1993.
Subject(s): Organometallic chemistry
Porphyrins
Hematoporphyrin
Metallocenes
Held by: Florida Atlantic University Libraries
Persistent Link to This Record: http://purl.flvc.org/fcla/dt/14940
Sublocation: Digital Library
Use and Reproduction: Copyright © is held by the author, with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
Use and Reproduction: http://rightsstatements.org/vocab/InC/1.0/
Host Institution: FAU
Is Part of Series: Florida Atlantic University Digital Library Collections.