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Synthesis and characterization of group IVB metallocene materials derived from hematoporphyrin IX
| Title: | Synthesis and characterization of group IVB metallocene materials derived from hematoporphyrin IX. |
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| Name(s): |
Rivalta, Alberto Enrico. Florida Atlantic University, Degree grantor Carraher, Charles E. Haky, Jerome E., Thesis advisor |
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| Type of Resource: | text | |
| Genre: | Electronic Thesis Or Dissertation | |
| Issuance: | monographic | |
| Date Issued: | 1993 | |
| Publisher: | Florida Atlantic University | |
| Place of Publication: | Boca Raton, Fla. | |
| Physical Form: | application/pdf | |
| Extent: | 114 p. | |
| Language(s): | English | |
| Summary: | New organometallic containing materials were synthesized by the reaction of Group IVB metallocene dichlorides of the form Cp2MCl2 where M = Ti, Ar, and Hf with Hematoporphyrin IX using the interfacial condensation polymerization technique. The structural characterization was accomplished using infrared and mass spectroscopy and elemental analysis. The results obtained from these techniques showed the presence of the metal ester and ether bonding as evidence that the reaction occurred. The product derived from titanocene dichloride, 12-A, exhibited growth inhibition characteristics towards the Candid albicans and Staphylococcus aureus microorganisms. From the preliminary metal adsorption studies it was shown that this product also bound nickel ions. | |
| Identifier: | 14940 (digitool), FADT14940 (IID), fau:11720 (fedora) | |
| Note(s): |
Charles E. Schmidt College of Science Thesis (M.S.)--Florida Atlantic University, 1993. |
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| Subject(s): |
Organometallic chemistry Porphyrins Hematoporphyrin Metallocenes |
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| Held by: | Florida Atlantic University Libraries | |
| Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/14940 | |
| Sublocation: | Digital Library | |
| Use and Reproduction: | Copyright © is held by the author, with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder. | |
| Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
| Host Institution: | FAU | |
| Is Part of Series: | Florida Atlantic University Digital Library Collections. |
