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Characterization of nickel electrodes for secondary batteries by means of electrochemical impedance spectroscopy

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Date Issued:
1991
Summary:
An automated procedure for integrated cycling and electrochemical impedance spectroscopy (EIS) testing of nickel sinter individualized pressure vessel electrodes for secondary nickel/hydrogen batteries was developed. Nickel electrodes from three major U.S. manufacturers were cycled under various conditions. The condition of the electrodes was monitored using both EIS and traditional electrochemical methods. In order to establish relationships between the status of the electrodes and the acquired impedance spectra, various cycling and electrode parameters were analyzed and compared with the EIS data. Nonlinear least squares (NLS) regression was used for analysis of the impedance data. An equivalent circuit was developed which produced good correlation with the impedance data at all states-of-charge and discharge rates. Problems with the experimental procedure which limit the validity of EIS testing were discussed.
Title: Characterization of nickel electrodes for secondary batteries by means of electrochemical impedance spectroscopy.
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Name(s): Nenov, Krassimir Petrov.
Florida Atlantic University, Thesis advisor
Lipka, Stephen M., Thesis advisor
College of Engineering and Computer Science
Department of Ocean and Mechanical Engineering
Type of Resource: text
Genre: Electronic Thesis Or Dissertation
Issuance: monographic
Date Issued: 1991
Publisher: Florida Atlantic University
Place of Publication: Boca Raton, Fla.
Physical Form: application/pdf
Extent: 156 p.
Language(s): English
Summary: An automated procedure for integrated cycling and electrochemical impedance spectroscopy (EIS) testing of nickel sinter individualized pressure vessel electrodes for secondary nickel/hydrogen batteries was developed. Nickel electrodes from three major U.S. manufacturers were cycled under various conditions. The condition of the electrodes was monitored using both EIS and traditional electrochemical methods. In order to establish relationships between the status of the electrodes and the acquired impedance spectra, various cycling and electrode parameters were analyzed and compared with the EIS data. Nonlinear least squares (NLS) regression was used for analysis of the impedance data. An equivalent circuit was developed which produced good correlation with the impedance data at all states-of-charge and discharge rates. Problems with the experimental procedure which limit the validity of EIS testing were discussed.
Identifier: 14777 (digitool), FADT14777 (IID), fau:11567 (fedora)
Collection: FAU Electronic Theses and Dissertations Collection
Note(s): College of Engineering and Computer Science
Thesis (M.S.E.)--Florida Atlantic University, 1991.
Subject(s): Impedance spectroscopy
Electrochemical analysis
Electric batteries--Electrodes
Held by: Florida Atlantic University Libraries
Persistent Link to This Record: http://purl.flvc.org/fcla/dt/14777
Sublocation: Digital Library
Use and Reproduction: Copyright © is held by the author, with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder.
Use and Reproduction: http://rightsstatements.org/vocab/InC/1.0/
Host Institution: FAU
Is Part of Series: Florida Atlantic University Digital Library Collections.