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FERROCENYLMETHYLATION OF 1,1-DIARYLALKENES
| Title: | FERROCENYLMETHYLATION OF 1,1-DIARYLALKENES. |
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| Name(s): |
FERNANDEZ, ROSA MIRTA Florida Atlantic University, Degree Grantor |
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| Type of Resource: | text | |
| Genre: | Electronic Thesis Or Dissertation | |
| Issuance: | monographic | |
| Date Issued: | 1977 | |
| Publisher: | Florida Atlantic University | |
| Place of Publication: | Boca Raton, Fla. | |
| Physical Form: | application/pdf | |
| Extent: | 207 p. | |
| Language(s): | English | |
| Summary: | The ferrocenylrnethylation of the following compounds was studied using (ferrocenylmethyl)trimethylammonium iodide: 1, 1-di(p-anisyl)- ethene (I), 1, 1-di(p- anisyl)propene (II), 1- (p- anisyl)-1-phenylethene (III), 1, 1- diphenylethene (IV), 1, 1- di(p- dimethylaminophenyl )ethene (V) and 1, 1-di(p-dimethylaminophenyl)propene (VI). I is ferrocenylmethylated exclu,sively on its side-chain, one or both vinyl hydrogens being replaced by ferrocenylmethyl groups depending on the ratio of ferrocenylmethylating agent to I, concentration of the reaction mixture, reaction time, solvent and temperature. II is substituted only on its side-chain to give a mono-ferrocenylmethylated product. III is ferrocenylmethylated slowly. IV fails to react. Mono-ferrocenylmethylation of V occurs principally on its side- chain; more extensive ferrocenylmethylation occurs both on the side-chain and on the rings at the position ortho to dimethylamino. VI reacts quite indiscriminately both on the side-chain and on the rings. | |
| Identifier: | 13837 (digitool), FADT13837 (IID), fau:10665 (fedora) | |
| Note(s): | Thesis (M.S.)--Florida Atlantic University, 1977. | |
| Subject(s): |
Chemistry--Research Chemistry, Organic Methylation |
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| Held by: | Florida Atlantic University Libraries | |
| Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/13837 | |
| Sublocation: | Digital Library | |
| Use and Reproduction: | Copyright © is held by the author with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder. | |
| Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
| Host Institution: | FAU | |
| Is Part of Series: | Florida Atlantic University Digital Library Collections. |
